控制点CGCS2000坐标的联测及解求

CGCS2000坐标系是我国目前精度最高的坐标系,其推广使用具有重大意义。文中在安装并学习美国高精度GPS基线处理软件GAMIT软件基础上,以4个无坐标信息观测墩为例,进行观测数据采集与数据处理方案的设计,以期获取4个观测墩的CGCS2000坐标。最终结果表明,各质量指标均满足限差要求,且平差后最弱边中误差满足《工程测量规范》(GB50026-2007)三等工程控制网的要求。     

Highly disordered ionic distribution in α-dicalcium silicate for structure relaxation

Dicalcium silicate, which is found in steelmaking slag for dephosphorization, exists as the hexagonal α phase at high temperatures. The α-dicalcium silicate forms a solid solution with tricalcium phosphate in the entire composition range, although the reason for high solubility of phosphorus remains unclear in view of the crystal structure. It has previously been reported that the crystal structure of α-dicalcium silicate consists of a symmetric arrangement of Ca²⁺ ions and SiO₄⁴⁻ tetrahedra, although other polymorphs exhibit asymmetric arrangements. However, because the occupation probability of each atomic site in the α polymorph is not limited to unity, it has not been qualified how these ions are exactly arranged. In this study, the ionic distribution in the α polymorph of dicalcium silicate was evaluated by first-principles calculation based on density functional theory (DFT), as well as by molecular dynamics (MD) simulation with a polarizable ion model optimized by DFT calculation. The results indicated that the completely symmetric ionic arrangement, as reported for the α phase, is the most unstable. Electronic-state calculation and MD simulation indicated that a highly disordered ionic arrangement spontaneously forms in the α-phase crystal for structure relaxation when held at high temperatures, or when phosphorus is incorporated.     

Phase evolution of a novel silicon-alumina-fused mullite-containing Ti2O3 refractory at 1300 °C in N2

A novel silicon-alumina-fused mullite-containing Ti₂O₃ composite refractory is prepared and sintered in the presence of solid carbon at 1300 °C in N₂. The sintered samples exhibit a functional gradient characteristic. The phase evolution can be described as follows: Passive and active oxidation of Si to form SiO₂ and SiO to reduce the partial pressure of oxygen. SiO(g) and Si react with N₂ to form Si₃N₄ respectively. As the temperature increases and the partial pressure of oxygen decreases, Ti₂O₃ reacts with CO and N₂ to form Ti(C,N)ss, which is accompanied by the release of O₂. Si₃N₄ fixes the O₂ and reacts to form Si₂N₂O, and Si₂N₂O reacts with Al₂O₃ to form O′-Sialon, thereby realizing the transformation from Si₃N₄ to Sialon. CO and residual carbon from the pyrolysis of phenolic resin react with SiO(s) and Si to form SiC. The dense layer formed by SiC and SiO₂ blocks the diffusion of external gas to the central parts of the samples, there is still free Si which can continue to react and transform into a non-oxide reinforcing phase. In this paper, the reaction models are presented.     

Phase composition and property evolution of (Yb1−xHox)2Si2O7 solid solution as environmental/thermal barrier coating candidates

RE disilicates are good candidates as environmental/thermal barrier coating for SiC_f/SiC composite in harsh gas turbine engines. We designed (Yb_1?xHo_x)₂Si₂O₇ solid solutions and studied mechanical properties, thermal properties, and water vapor resistance. Powders with different compositions were synthesized by pressureless sintering, and bulk samples were prepared by Spark Plasma Sintering (SPS). Polymorphic changes with temperature and composition of the solid solutions were examined. Through doping Ho into Yb₂Si₂O₇, water vapor corrosion resistance is significantly promoted, and thermal expansion coefficient is maintained close to that of Si-based ceramics. Compared with host disilicates, thermal conductivity of solid solutions are decreased, and mechanical properties, including Vickers hardness and fracture toughness, are increased. A two-phase domain is found at (Yb_1/2Ho_1/2)₂Si₂O₇, and the γ to δ phase transition of Ho₂Si₂O₇ is observed during SPS. Among all samples, γ-(Yb_1/3Ho_2/3)₂Si₂O₇ possesses superior high temperature stability, and excellent water vapor resistance, indicating its performance as environmental/thermal barrier coating.     

Gd-Bi-M-Ce-O (M = Cu,Zr, Ni,Co, Mn) ceria-based solid solutions for low temperature CO oxidation

Ceria based solid solutions doped by Gd, Bi, and the third dopant were synthesized by the co-precipitation method with ultrasonic treatment, followed by calcination at the temperature of 500°С. Characterization of the synthesized nanosystems by XRD, TEM, TG, Raman spectroscopy, FTIR, XPS was carried out. It is shown that all obtained powders of solid solutions crystallized into a cubic structure of the fluorite type, with an average particle size of 5–15 nm. The samples had a mesoporous structure of the pore diameter of 2–5 nm. The catalytic activity of Gd-Bi-M-Ce-O (M = Cu, Zr, Ni, Co, Mn) solid solutions was carried out. The catalyst Gd_0.05Bi_0.15Mn_0.20Ce_0.60O₂ has the lowest oxidation temperature.     

3-D Elasticity Solutions of Layered Rectangular Plates Subjected to Thermo-Loads

According to the exact three-dimensional (3D) thermoelasticity theory, the elasticity solution of the simply-supported layered rectangular plates subjected to steady temperature loads was studied. An analytical method was developed to solve the temperature, stress and displacement fields in the plate. Firstly, the general solutions of the temperature, displacements and stresses in a simply-supported isotropic layer were obtained by solving the 3-D heat conduction equation and the 3-D equations of elasticity respectively, which were expressed in the form of double Fourier series. Then, the temperature, displacement and stress relationships between the upper surface and the lower surface of the isotropic layer were derived. Based on the continuity of the temperature, the heat flux, the displacements and the stresses on the interface of two adjacent layers with different material properties, the recursive formulae of temperature, displacements and stresses between the bottom layer and the top layer of the layered plate were obtained by using the transfer matrix method. The unknown coefficients in the solutions for every layer were uniquely determined by the upper surface and lower surface conditions of the plate. The distributions of the temperature, displacements and stresses in the plate were given by substituting the unknown coefficients obtained back to the recurrence formulae and the solutions. The convergence of the solutions was checked with respect to the number of the terms of series. Comparing the results with those obtained from the finite element method, the correctness of the present method was verified. Finally, the effects of surface temperatures, plate thickness, layer number and material properties of each layer on the distributions of the temperature, displacements and stresses in the plates were discussed in detail.     

PBS-co-DEG与热塑性淀粉共混膜的性能研究

采用流延法制备了不同二甘醇(DEG)含量的聚丁二酸丁二醇二甘醇共聚酯(PBS-co-DEG)与热塑性淀粉(TPS)共混的复合膜,通过核磁共振氢谱仪、傅里叶变换红外光谱仪、凝胶渗透色谱仪、热重分析仪、紫外–可见分光光度计、偏光显微镜等对共聚酯的结构及复合膜的性能进行了表征和测试,采用N435脂肪酶对复合膜进行了降解实验。结果表明,随DEG含量的增加PBS-co-DEG/TPS复合膜的亲水性、光透过率和断裂伸长率均有所增加,热稳定性变化不明显;与PBS/TPS复合膜相比,PBS-co-DEG/TPS复合膜的酶降解速率显著提高。     

Closed form solution for predicting the horizontal capacity of masonry portal frames through limit analysis and comparison with experimental test results

The paper deals with the problem of evaluating the in-plane seismic capacity of unreinforced masonry portal frame, which can be considered the basic structural element in historical buildings. In particular, the Limit Analysis approach is used to provide simplified “closed form” expressions of the horizontal collapse multiplier, also taking into account the eventual contribution of steel tie rods. Both sliding shear and shear diagonal cracking are also considered in order to take into account the shear failure modes of the pier walls.The proposed formulations have been used for performing an extensive parametric analysis, with the aim of studying the effect of both geometry and vertical/horizontal loading distributions on the portal horizontal strength. Furthermore, the influence of the steel tie-rods has been addressed in order to understand their effectiveness on the portal seismic capacity.A comparison with the results of experimental tests on full-scale portal frames is also provided in terms of in-plane collapse multiplier and failure mechanism aimed to validate the proposed “closed form” expressions.Major outcome of this study is a simple rule of thumb, which can be used for the straightforward assessment of the horizontal strength of simple masonry structures, and for verifying the results of more complex structural analyses such as the nonlinear static analysis.